Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
NEW METHODS AND REAGENTS IN ORGANIC SYNTHESIS. 37. TRIMETHYLSILYLDIAZOMETHANE, A CONVENIENT REAGENT FOR THE PREPARATION OF VINYLSILANES FROM ALKANESULFONYL CHLORIDES
Toyohiko Aoyama, Sachio Toyama, Naoko Tamaki, Takayuki Shioiri
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Keywords: episulfone
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1983 Volume 31 Issue 8 Pages 2957-2959

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Abstract

Trimethylsilyldiazomethane reacts smoothly with alkanesulfonyl chlorides in the presence of triethylamine to give vinylsilanes.

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© The Pharmaceutical Society of Japan
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